流态固化淤泥干湿循环耐久性试验研究

    Experimental study on wetting-drying cycle durability of flowable solidified sludge

    • 摘要: 复合型流态土固化剂(CFSS)制备的流态固化淤泥具有高流动性、自密实和强度可控等特点,但其干湿循环耐久性尚未研究。采用CFSS固化淤泥,研究了干湿循环次数和CFSS掺量对流态固化淤泥的影响,通过XRD和SEM分析了干湿循环耐久性微观演化机理。结果表明:随干湿循环次数增加,流态固化淤泥表观影响、质量损失率和含水率均逐渐增大,干密度均逐渐减小,UCS先减小后轻微增大再逐渐减小至趋于稳定;随CFSS掺量增大,干湿循环作用对试样表观的影响逐渐减小,试样质量损失逐渐降低,高掺量试样的质量稳定性较好,试样含水率减小,干密度和UCS逐渐增大,干湿稳定系数与CFSS掺量呈良好的线性关系。随干湿循环次数增加,流态固化淤泥的钙矾石衍射峰强度降低,形状由柱状向针状转变,排列混乱,分布密度降低,孔隙数量增多,孔径增大,密实程度降低;随CFSS掺量增大,钙矾石衍射峰强度增大,土体的微孔隙减少,生成的水化产物更多,试样密实程度增加;从微观层面较好地解释了宏观特性的变化规律。CFSS固化淤泥具有良好的干湿循环耐久性,为CFSS的工程应用提供理论支持。

       

      Abstract: Flowable solidified sludge prepared with a composite Flowable soil stabilizer (CFSS) exhibits properties such as high fluidity, self-compaction, and controllable strength; however, its wetting-drying cycle durability has not been thoroughly investigated. In this study, sludge was stabilized using CFSS to investigate the effects of wetting-drying cycles and the CFSS content on the performance of flowable solidified sludge. The microstructural evolution mechanism responsible for its wetting-drying cycle durability is analyzed using XRD and SEM. The results demonstrated that with increasing wetting-drying cycles, the surface deterioration, mass loss rate, and water content of the flowable solidified sludge progressively increase, while its dry density decreases. The UCS initially decreases, follows by a slight increase, then underwent goes a gradual reduction until it eventually stabilizes. With increasing CFSS content, the detrimental effects of wetting-drying cycles on the specimens' appearance are mitigated, mass loss is reduced, and specimens with higher CFSS content exhibit superior mass stability. Furthermore, water content decreases, whereas dry density and UCS increase progressively. A linear correlation is observed between the wetting-drying stability coefficient and the CFSS content. After five wetting-drying cycles, the intensity of the ettringite diffraction peaks decreases, with the crystal morphology transitioning from columnar to acicular, disordered arrangement, and lower distribution density. Concurrently, the number of pores increases, the pore size enlarges, and the compactness decreases. An increase in CFSS content leads to higher ettringite diffraction peak intensity, a reduction in soil micropores, the formation of more hydration products, and consequently, enhances specimen compactness. These microstructural changes provide a coherent explanation for the observed macroscopic behavior. CFSS-stabilized sludge exhibits satisfactory wetting-drying cycle durability, which provides theoretical support for the engineering application of CFSS.

       

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