赤泥基固化剂研发及固化铅污染土试验研究

    Development of red mud-based binder and experimental study on solidification of lead-contaminated soil

    • 摘要: 在环境岩土工程中,应用赤泥基固化剂治理铅污染土能够取得显著的经济效益和环境效益。采用30%的赤泥、40%的矿渣/粉煤灰/钢渣,并调整电石渣和磷石膏的比例,制备了3种赤泥基固化剂,研究其力学性能和微观机理。在此基础上,将研发的赤泥基固化剂用于铅污染土固化,评价固化土的力学性能和毒性浸出行为。结果表明,由30%赤泥、40%矿渣、20%电石渣及10%磷石膏制备的胶砂试样强度表现最佳,其养护28 d后的胶砂无侧限抗压强度达23.8 MPa;过量磷石膏会导致钙矾石生成过多,引发大量膨胀裂缝,导致力学性能劣化;在高铅污染浓度下,固化土的无侧限抗压强度由未固化时的0.27 MPa提升至4.75 MPa,铅离子浸出浓度从3.83 mg/L降低至0.34 mg/L。

       

      Abstract: In environmental geotechnical engineering, the use of red mud-based binders for the remediation of lead-contaminated soil offers significant economic and environmental benefits. Three types of red mud-based binders are prepared by incorporating 30% red mud and 40% slag, fly ash, or steel slag, while adjusting the proportions of carbide slag and phosphogypsum. Their mechanical properties and micro-mechanisms are investigated. The developed binders are then applied to stabilize lead-contaminated soils, and the mechanical performance and leaching behavior of the stabilized soil were evaluated. The results show that the mortar prepared with 30% red mud, 40% slag, 20% carbide slag, and 10% phosphogypsum exhibited the highest strength, achieving an unconfined compressive strength (UCS) of 23.8 MPa after 28 days of curing. Excessive phosphogypsum is found to induce overproduction of ettringite, leading to significant expansive cracking and subsequent deterioration of mechanical strength. Under the high lead contamination level, the UCS of the stabilized soil increases markedly from 0.27 MPa (untreated) to 4.75 MPa, while the Pb2+ leaching concentration dropped from 3.83 mg/L to 0.34 mg/L.

       

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