胡阳, 周实际, 徐杨, 林恩峰, 曾施敏, 田明阳, 林敏立, 杜延军. 磷基固化剂处理矿区酸性重金属污染土现场试验研究[J]. 岩土工程学报. DOI: 10.11779/CJGE20241223
    引用本文: 胡阳, 周实际, 徐杨, 林恩峰, 曾施敏, 田明阳, 林敏立, 杜延军. 磷基固化剂处理矿区酸性重金属污染土现场试验研究[J]. 岩土工程学报. DOI: 10.11779/CJGE20241223
    Field trial of solidifying/stabilizing multi-heavy metals-contaminated soil using phosphorus-based binders[J]. Chinese Journal of Geotechnical Engineering. DOI: 10.11779/CJGE20241223
    Citation: Field trial of solidifying/stabilizing multi-heavy metals-contaminated soil using phosphorus-based binders[J]. Chinese Journal of Geotechnical Engineering. DOI: 10.11779/CJGE20241223

    磷基固化剂处理矿区酸性重金属污染土现场试验研究

    Field trial of solidifying/stabilizing multi-heavy metals-contaminated soil using phosphorus-based binders

    • 摘要: 针对某金矿酸性废液收集库重金属(铁、锰)复合污染土的固化稳定化修复工程开展了现场试验研究。采用12%的生物质固废牛骨粉复配电石渣(SS-H)、过磷酸钙复配电石渣(SS-E)两种固化剂固化污染土,研究现场污染土固化后的重金属浸出浓度、无侧限抗压强度、pH、干密度、贯入指数(DCPI)、重金属赋存形态,明确SS-H和SS-E的土体固化和重金属稳定化效果。结果表明:①养护28d后,SS-H和SS-E均可显著降低污染土的重金属浓度,且浸出浓度可满足地下水Ⅲ类质量标准(GB/T 14848—2017)的限制要求。②SS-H对锰的稳定化效果更好显著,锰的浸出浓度由23 mg/L降低至0.02 mg/L;SS-E对铁的修复效果更好,铁的浸出浓度由34.3 mg/L降低至0.04 mg/L。③SS-H和SS-E均能有效提高固化土的强度。现场试验28天后,固化土体平均DCPI较处理前分别降低了93.1%和93.2%。SS-H和SS-E两种固化剂可有效地固定酸性复合污染土的重金属,且提高污染土力学性能。④相比污染土,SS-H和SS-E固化土中水溶态Mn的占比分别由16.5%降低至0.19%和0.34%,修复前后Fe的形态变化不显著。

       

      Abstract: Field tests were conducted to evaluate the effectiveness of binders (SS-H and SS-E) for solidifying/stabilizing iron (Fe) and manganese (Mn) contaminated soils at a gold mining acid waste collection reservoir. The field-stabilized soils were subjected to the toxicity characteristic leaching procedure (TCLP), pH, dry density, dynamic cone penetrometer tests, and heavy metal speciation analysis. The results indicated that field stabilization using SS-H and SS-E significantly reduced the leached concentrations of Fe and Mn, with the leached concentrations of Fe and Mn being below the national groundwater quality standard (GB/T 14848—2017, Class III). SS-H was more effective in immobilizing Mn, with its leached concentration decreasing from 23 mg/L to 0.02 mg/L. SS-E was more effective in immobilizing Fe, reducing its leached concentration from 34.3 mg/L to 0.04 mg/L. Both SS-H and SS-E significantly improved the strength of the solidified soils. The dynamic cone penetration index of SS-H and SS-E solidified soils decreased by 93.1% and 93.2%, respectively, as compared to the untreated soils. The results demonstrate that both SS-H and SS-E binders are promising in solidifying/stabilizing multi-heavy metals contaminated soils with low pH.

       

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