协同固化作用下石油污染土的黏温效应研究

    Viscosity-temperature effects of petroleum-contaminated soil under synergistic solidification

    • 摘要: 温度影响着土中石油污染物的赋存形态,是引发结构失稳和环境二次污染的关键因素,石油污染土黏温特性的合理调控是推进其工程再利用过程中需解决的科学问题。提出黏度指数改进剂协同无机材料进行石油污染土固化的处置方法,依托流变仪及改进的温控直剪蠕变和液塑限联合测定试验平台,从石油及石油污染土双重角度,分析黏度指数、黏滞系数和稠度指标随温度的演变规律,评价黏温效应,构建黏温特性调控方法。结果表明:石油及石油污染土的黏性状态均受温度影响显著,同污染浓度下石油污染土在20℃温差下的塑性指数变化率高达31.83%,且其在80℃下的黏滞系数较10℃的平均降低率为53.82%。黏度指数改进剂有助于增大石油黏度指数,改善石油温敏性。7% T614(乙丙共聚物)+7% T602HB(聚甲基丙烯酸酯)协同无机材料固化石油污染土相邻温度间黏滞系数和稠度指标变化率范围均在5%以内,且10~80℃温度下总体变化范围在10%以内。协同固化作用下的调控率(达85.42%)均高于单一固化方式的累加,黏度指数改进剂和无机材料在调控效能方面相辅相成,改进剂优化土中石油分布,解决石油对固化反应的干扰,提升吸附和固化反应充分性;无机材料固化优化土体结构,增强了改进剂与石油间的作用效果。黏度指数改进剂与无机材料的协同固化实现了石油污染土宽温域范围的调控,有助于提升其工程再利用过程中的稳定性。

       

      Abstract: Temperature affects the occurrence form of petroleum contaminants in the soil, which is a key factor causing the structural instability and secondary environmental contamination. The reasonable control of the viscosity change under temperatures is a scientific problem for the engineering reuse of the petroleum-contaminated soil. The method of viscosity index improvers combined with inorganic materials for solidifying the petroleum-contaminated soil is proposed in this study. The evolution of the viscosity index, viscosity coefficient and consistency index with the temperature is analyzed from the perspective of the petroleum and petroleum-contaminated soil. The viscosity-temperature effects are evaluated, and the relative regulation method is established. The results show that the viscosities of the petroleum and petroleum-contaminated soil are significantly affected by the temperature. The plastic index change rate of the petroleum-contaminated soil at 20℃ is as high as 31.83%, and the viscosity coefficient at 80℃ is 53.82% lower than that at 10℃. The viscosity index improver is helpful in increasing the viscosity index of the petroleum and improving its occurrence stability. As for the petroleum-contaminated soil solidified by 7% of T614 (ethylene propylene copolymer), 7% of T602HB (polymethyl methacrylate) and inorganic materials, the change rates of the viscosity coefficient and consistency index between adjacent temperatures are within 5%, and the overall change range from 10℃ to 80℃ is within 10%. The regulation rate under the synergistic solidification (85.42%) is higher than the accumulation of the single solidified method. The viscosity index improvers and inorganic materials complement each other in the regulation efficiency. The improver optimizes the petroleum distribution in the soil, which can improve the sufficiency of adsorption and solidified reaction. Meanwhile, the solidification of inorganic materials enhances the density of soil structure and strengthens the action of the viscosity index improvers and petroleum. The synergistic solidification of the viscosity index improvers and inorganic materials realizes the regulation of the petroleum-contaminated soil in a wide temperature range, which helps to improve the stability of the petroleum-contaminated soil in the process of engineering reuse.

       

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