康农波, 郑文杰, 胡文乐, 王艺涵. 新型凝胶电极强化铜铅污染黄土电动去除效率的试验及内在机理研究[J]. 岩土工程学报, 2025, 47(7): 1484-1493. DOI: 10.11779/CJGE20240249
    引用本文: 康农波, 郑文杰, 胡文乐, 王艺涵. 新型凝胶电极强化铜铅污染黄土电动去除效率的试验及内在机理研究[J]. 岩土工程学报, 2025, 47(7): 1484-1493. DOI: 10.11779/CJGE20240249
    KANG Nongbo, CHENG Wenchieh, HU Wenle, WANG Yihan. Experimental study on electrokinetic removal efficiency of copper-lead- contaminated loess enhanced by novel hydrogel electrodes and its inherent mechanism[J]. Chinese Journal of Geotechnical Engineering, 2025, 47(7): 1484-1493. DOI: 10.11779/CJGE20240249
    Citation: KANG Nongbo, CHENG Wenchieh, HU Wenle, WANG Yihan. Experimental study on electrokinetic removal efficiency of copper-lead- contaminated loess enhanced by novel hydrogel electrodes and its inherent mechanism[J]. Chinese Journal of Geotechnical Engineering, 2025, 47(7): 1484-1493. DOI: 10.11779/CJGE20240249

    新型凝胶电极强化铜铅污染黄土电动去除效率的试验及内在机理研究

    Experimental study on electrokinetic removal efficiency of copper-lead- contaminated loess enhanced by novel hydrogel electrodes and its inherent mechanism

    • 摘要: 以人工配制铜铅污染黄土为研究对象,采用团队自制新型凝胶电极并结合电动修复技术,研究污染黄土铜铅离子迁移规律,以土工合成材料(EKG)和新型凝胶电极为电动修复的对照组,通过采用新型凝胶电极结合不同强化手段的联用方式下,分析试验过程中电动修复参数的演变规律,揭示不同的强化方法对重金属离子去除效率的影响及内在机理。结果表明:酸预处理结合阴极酸碱度的自主调控能够显著降低阴极附近的沉淀现象和降低pH值,致使整个环境体系利于阴阳离子定向迁移,从而提高电流和温度,强化电动修复去除效率,进而表明该方法去除铜铅重金属的有效性及强化去除的可行性,而交换电极与点加酸联用手段显著降低阴极附近离子的聚集问题;基于新型凝胶电极的微观机理,该电极具有极小的电化学极化、低电阻和高导电性等方面的优越性能。因此,本研究提出了一种采用新型凝胶电极结合新的强化手段提高去除效率的方法,并解决电动过程中“电化学极化”和“聚焦效应”问题。

       

      Abstract: In this study, a novel hydrogel electrode is used to investigate the migration law of copper (Cu) and lead (Pb) in artificially prepared Cu- and Pb-contaminated loess. The novel hydrogel electrode is compared with the geosynthetic material electrode (EKG) in electrokinetic (EK) remediation. The evolution law of EK remediation parameters is analyzed by using a novel hydrogel electrode combined with different strengthening methods, and the influences of different strengthening methods on the removal efficiency of heavy metal ions and the internal mechanism are revealed. The results show that acid pretreatment combined with autonomous pH regulation of the cathode can significantly reduce the focusing phenomenon surrounding the cathode, facilitating the electromigration of cations and anions and enhancing the removal efficiency. It proves the proposed method's feasibility and effectiveness of the Cu and Pb removals. The combination of the exchange electrode and point acid can significantly reduce the accumulation of ions near the cathode. The novel hydrogel electrode has excellent performance in terms of the minimal electrochemical polarization, low resistance and high conductivity based on its microscopic analysis. Therefore, a novel hydrogel electrode combined with the strengthening methods is proposed to improve the removal efficiency and solve the electrochemical polarization and focusing effects in the EK process.

       

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