芮大虎, 王嘉义, 张军, 潘卫东, 王淼. 基于赤玉土强冻胀特性提高重金属污染黏性土淋洗效率研究[J]. 岩土工程学报, 2025, 47(7): 1373-1381. DOI: 10.11779/CJGE20231295
    引用本文: 芮大虎, 王嘉义, 张军, 潘卫东, 王淼. 基于赤玉土强冻胀特性提高重金属污染黏性土淋洗效率研究[J]. 岩土工程学报, 2025, 47(7): 1373-1381. DOI: 10.11779/CJGE20231295
    RUI Dahu, WANG Jiayi, ZHANG Jun, PAN Weidong, WANG Miao. Improvement of washing efficiency of heavy metal-contaminated clayey soils based on strong frost-heave characteristics of Akadama soil[J]. Chinese Journal of Geotechnical Engineering, 2025, 47(7): 1373-1381. DOI: 10.11779/CJGE20231295
    Citation: RUI Dahu, WANG Jiayi, ZHANG Jun, PAN Weidong, WANG Miao. Improvement of washing efficiency of heavy metal-contaminated clayey soils based on strong frost-heave characteristics of Akadama soil[J]. Chinese Journal of Geotechnical Engineering, 2025, 47(7): 1373-1381. DOI: 10.11779/CJGE20231295

    基于赤玉土强冻胀特性提高重金属污染黏性土淋洗效率研究

    Improvement of washing efficiency of heavy metal-contaminated clayey soils based on strong frost-heave characteristics of Akadama soil

    • 摘要: 冻融协同化学淋洗能够去除黏性土中重金属污染物,但是冻结过程中淋洗液摄入量少,存在淋洗效率低下的问题。利用改善黏性土冻胀性增加水分迁移量以提高淋洗效率的思路,以重金属污染黏性土为研究对象,选用强冻胀性赤玉土为掺料土,开展了土柱冻融-淋洗试验。结果表明,相同冻结条件下赤玉土的冻胀率为124.48%,其冻胀量和吸水量分别为黏性土的5.85倍和4.82倍,具有极强冻胀性;赤玉土对Pb、Cd吸附能力较弱,可以重复利用;掺入赤玉土后黏性土的冻胀量和吸水量显著增加,最大增幅分别为130.91%,113.39%;经3次冻融后,Pb、Cd去除率分别达到57.51%,66.77%,相较未掺入赤玉土组提升173.73%,113.94%。SEM试验表明冻融循环后赤玉土结构破碎严重且孔隙数量增加,有利于水分的迁移和储存。赤玉土作为掺料土提高冻融-淋洗效率的方法在实际工程应用中具有易操作性和普适性,为季节冻土区重金属污染黏性土修复提供了一个新的思路。

       

      Abstract: The freeze-thaw synergistic chemical washing can remove heavy metal contaminants from clayey soils. However, the intake of eluent is low during the freezing process, resulting in low washing efficiency. Based on the idea of improving the frost heave of clayey soils and increasing water migration to improve the leaching efficiency, the freeze-thaw-leaching tests on soil columns are carried out by taking heavy metal-contaminated clayey soils as the research object and selecting strong frost-heave Akadama soil as the admixture. The results indicate that under the same freezing conditions, the frost-heave rate of Akadamas soil 124.48%, with the corresponding increase in the frost-heave amount and water intake of 5.85 times and 4.82 times that of clayey soils, respectively. This indicates an extremely strong frost-heave characteristic. The adsorption capacity of Akadama soil for Pb and Cd is weak, and it can be reused. After incorporating Akadama soil, the frost-heave amount and water intake of clayey soils significantly increase, with the maximum increments of 130.91% and 113.39%, respectively. After three freeze-thaw cycles, the removal rates of Pb and Cd reach 57.51% and 66.77%, respectively, representing an increase of 173.73% and 113.94% compared to those of the control group without Akadama soil. The SEM tests show that the structure of Akadama soil is severely broken and the number of pores increases, which is conducive to the migration and storage of water after freeze-thaw cycles. The method of using Akadama soil as an admixture soil to improve the freeze-thaw leaching efficiency has operability and universality in practical engineering applications. It provides a new approach for the remediation of heavy metal-contaminated clayey soils in seasonal frozen regions.

       

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