Advanced Search
  • 全国中文核心期刊
  • 中国科技核心期刊
  • 美国工程索引（EI）收录期刊
  • Scopus数据库收录期刊
Volume 33 Issue zk1
Turn off MathJax
Article Contents
Abstract
References
Related Articles
WANG Yan, TANG Xiao-wu, WANG Heng-yu, LIU Wei. Sorption and desorption behaviors of heavy metal Mn(II) on loess soil[J]. Chinese Journal of Geotechnical Engineering, 2011, 33(zk1): 369-373.
Citation: WANG Yan, TANG Xiao-wu, WANG Heng-yu, LIU Wei. Sorption and desorption behaviors of heavy metal Mn(II) on loess soil[J]. Chinese Journal of Geotechnical Engineering, 2011, 33(zk1): 369-373.
shu

Sorption and desorption behaviors of heavy metal Mn(II) on loess soil

  • MOE Key Laboratory of Soft Soils and Geoenvironmental Engineering, Zhejiang University, Hangzhou 310058, China

More Information
  • Received Date: April 26, 2011
  • Published Date: November 30, 2011
    Graphical Abstract
    • Abstract
  • Manganese is a trace heavy metal. Toxic effect will be caused by excessive intake of manganese. The control of manganese discharge into environment has been attracted much attention recently. Loess soil is used to study the behaviors of removing Mn(II) from aqueous solutions due to its low cost and easy availability. Factors including reaction time, concentration of Mn(II), temperature and complexing agent nitriletriacetic acid (NTA) are studied. The adsorption of Mn(II) on loess soil is a fast process and can reach equilibrium within 1 h. The kinetic data fit the pseudo-second order kinetics model very well, and the reaction rate decreases with the increasing initial concentration of Mn(II). The adsorption capacity of Mn(II) on loess soil is determined to be 7.829 mg/g, and high temperature favors the adsorption process. NTA has contribution on the desorption of Mn(II) from loess soil. The higher concentration of NTA, the more Mn(II) is desorbed. When the amount of Mn(II) laden in loess soil is small, nearly all Mn(II) can be desorbed from loess soil. Clay minerals and organic matter in loess play important roles in Mn(II) adsorption, and ion exchange is the main adsorption mechanism. The results provide an evidence for loess soil as containment barrier system and as adsorbent removing heavy metal contamination in aquatic environment. The introducing of NTA has a certain reference value for remediation of contaminated soil.
    • FullText(HTML)
    • References (14)
  • [1]
    BAMSFORTH S M, MANNING D A C, SINGLETON I, et al. Manganese removal from mine waters: investigating the occurrence and importance of manganese carbonates[J]. Applied Geochemistry, 2006 , 21 (8) : 1274 – 1287.
    [2]
    SHARMA Y C, UMA, SINGH S N, et al. Fly ash for the removal of Mn(II) from aqueous solutions and wastewaters[J]. Chemical Engineering Journal, 2007 , 132 (1-3) : 319 – 323.
    [3]
    TIWARI D, YU M R, KIM M N, et al. Potential application of manganesecoated sand in the removal of Mn(II) from aqueous solutions[J]. Water Science and Technology, 2007 , 56 (7) : 153 – 160.
    [4]
    GB3838 — 2002 地表水环境质量标准 [S]. 2004. (GB3838 — 2002 Environmental quality standard for surface water[S]. 2004. (in Chinese))
    [5]
    GB8978 — 1996 污水综合排放标准 [S]. 1997. (GB8978 — 1996 Integrated water discharge standard[S]. 1997. (in Chinese))
    [6]
    TANG X W, LI Z Z, CHEN Y M, et al. Removal of Cu(II) from aqueous solution by adsorption on Chinese quaternary loess: kinetics and equilibrium studies[J]. Journal of Environmental Science and Health Part A, 2008, 43 (7) : 1 – 13.
    [7]
    TANG X W, LI Z Z, CHEN Y M, et al. Removal of Zn(II) from aqueous solution with natural Chinese loess: behaviors and affecting factors[J]. Desalination, 2009, 249 (1) : 49 – 57.
    [8]
    LI Z Z, TANG X W, CHEN Y M, et al. Sorption behavior and mechanism of Pb ( II) on Chinese loess[J]. Journal of Environmental Engineering-ASCE, 2009, 135 (1) : 58 – 67.
    [9]
    WANG Y, TANG X W, CHEN Y M, et al. Adsorption behavior and mechanism of Cd(II) on loess soil from China[J]. Journal of Hazardous Materials, 2009, 172 (1) : 30 – 37.
    [10]
    THOMAS E. Biodegradation of metal-complexing aminopolycarboxylic acids[J]. Journal of Bioscience and Bioengineering, 2001, 92 (2): 89 – 97.
    [11]
    DO D D. Adsorption analysis: equilibrium and kinetics[M]. London: Imperial College Press, 1998.
    [12]
    GILES C H, SMITH D A. A general treatment and classification of the solute sorption isotherms. I. Theoretical [J]. Journal of Colloid and Interface Science, 1974, 47 (3) : 755 – 765.
    [13]
    KILISLIOGLU A, BILGIN B. Thermodynamic and kinetic investigations of uranium adsorption on amberlite IR-118H resin[J]. Applied Radiation and Isotopes, 2003, 58 (2) : 155 – 160.
    [14]
    ÖZCAN A, ÖNCÜ E M, ÖZCAN A S. Kinetics, isotherm and thermodynamic studies of adsorption of Acid Blue 193 from aqueous solutions onto natural sepiolite[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2006, 277 (1-3) : 90 – 97.
    • Related Articles

  • Related Articles

    [1]Field test insights on mechanical behavior of ground around a large deformed shield tunnel rehabilitated by grouting[J]. Chinese Journal of Geotechnical Engineering. DOI: 10.11779/CJGE20240680
    [2]FAN Ke-wei, LIU Si-hong, XU Si-yuan, WANG Jian-lei. Field tests on retaining wall constructed with soilbags filled with clayey soils[J]. Chinese Journal of Geotechnical Engineering, 2018, 40(12): 2341-2348. DOI: 10.11779/CJGE201812024
    [3]SHAO Sheng-jun, LI Jun, LI Guo-liang, WANG Xin-dong, JIN Bao-cheng, SHAO Shuai. Field immersion tests on tunnel in large-thickness collapsible loess[J]. Chinese Journal of Geotechnical Engineering, 2018, 40(8): 1395-1404. DOI: 10.11779/CJGE201808004
    [4]LIAO Shao-ming, MEN Yan-qing, XIAO Ming-qing, ZHANG Di. Field tests on longitudinal stress relaxation along shield tunnel in soft ground[J]. Chinese Journal of Geotechnical Engineering, 2017, 39(5): 795-803. DOI: 10.11779/CJGE201705003
    [5]GUO Chao, FU Bai-yong, YUAN Hong, GONG Wei-ming. Application and field tests of cap-pile combined foundation with reversed construction[J]. Chinese Journal of Geotechnical Engineering, 2016, 38(11): 2085-2092. DOI: 10.11779/CJGE201611019
    [6]LIAO Shao-ming, MEN Yan-qing, ZHAO Guo-qiang, XU Wei-zhong. Mechanical behaviors and field tests of steel sleeves during shield receiving[J]. Chinese Journal of Geotechnical Engineering, 2016, 38(11): 1948-1956. DOI: 10.11779/CJGE201611003
    [7]LIAO Shao-ming, MEN Yan-qing, ZHANG Di, XU Yong. Field tests on mechanical behaviors during assembly of segmental linings of Qianjiang tunnel[J]. Chinese Journal of Geotechnical Engineering, 2015, 37(1): 156-164. DOI: 10.11779/CJGE201501019
    [8]HE Changming, ZOU Jinfeng, LI Liang. Field tests on measurement of dynamic stress of dynamic compaction[J]. Chinese Journal of Geotechnical Engineering, 2007, 29(4): 628-632.
    [9]GARTUNG Erwin, HENKEN MELLIES Ulrich, RAMKE Hans Gunter, HU Yifeng. Field tests on landfill covers for evaluation of performance of mineral cover systems[J]. Chinese Journal of Geotechnical Engineering, 2006, 28(3): 403-409.
    [10]ZHANG Mingju, GUO Zhongxian. Research on behaviors of soil nailing by field test[J]. Chinese Journal of Geotechnical Engineering, 2001, 23(3): 319-323.
    • Supplements (0)

Catalog

    Get Citation
    PDF
    XML
    Article views (1427) PDF downloads (620) Cited by()
    Related
    Copyright © 2010 Editorial By Chinese Journal of Geotechnical Engineering 苏ICP备05007122号-11公安联网备案号：32010602011255
    Editorial Office address：34 Hujuguan,Nanjing 210024,ChinaPostal Code：210024Tel：025-85829534，85829556E-mail: ge@nhri.cn

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return