• 全国中文核心期刊
  • 中国科技核心期刊
  • 美国工程索引(EI)收录期刊
  • Scopus数据库收录期刊
ZHU Zhangwen, FENG Shijin. Application and analysis of horizontal permeable reaction barrier in risk mitigation of VOC vapor in contaminated sites[J]. Chinese Journal of Geotechnical Engineering, 2023, 45(8): 1693-1702. DOI: 10.11779/CJGE20220547
Citation: ZHU Zhangwen, FENG Shijin. Application and analysis of horizontal permeable reaction barrier in risk mitigation of VOC vapor in contaminated sites[J]. Chinese Journal of Geotechnical Engineering, 2023, 45(8): 1693-1702. DOI: 10.11779/CJGE20220547

Application and analysis of horizontal permeable reaction barrier in risk mitigation of VOC vapor in contaminated sites

More Information
  • Received Date: May 01, 2022
  • Available Online: February 23, 2023
  • The horizontal permeable reaction barrier (HPRB) is a passive remediation technology for the volatile organic compound (VOC) vapor in the vadose zone. It has the advantage of consuming less energy during the operation. And it can be used as a long-term risk control measure for the large-scale VOC contaminated sites. A transient analytical model is proposed in this study to simulate the VOC vapor migration in the layered soil containing a layer of the HPRB. The Laplace transformation is adopted to derive the general solution in the Laplace domain, and then the Laplace inversion of the numerical Talbot method is adopted to derive the semi-analytical solution of the VOC vapor migration. It is found that the HPRB is more suitable for the contaminated sites with low effective diffusivity soil. The large depth of the HPRB is not conducive to the removal of the VOC vapor. The increase of thickness of the HPRB enhances the removal of the VOC vapor. The increase of the source concentration decay rate can reduce the peak value of the VOC concentration in the contaminated sites. The neglect of the source decay can lead to the excessively conservative design of the HPRB. Finally, the design procedure of the depth and thickness of the HPRB is proposed.
  • [1]
    US Environmental Protection Agency. Petroleum Hydrocarbons and Chlorinated Solvents Differ in Their Potential for Vapor Intrusion[M]. Washington, DC: US Environmental Protection Agency, 2012.
    [2]
    刘惠, 陈奕. 有机污染土壤修复技术及案例研究[J]. 环境工程, 2015, 33(增刊1): 920-923. https://www.cnki.com.cn/Article/CJFDTOTAL-HJGC2015S1230.htm

    LIU Hui, CHEN Yi. Organic contaminated soil treatment technologies and remediation practices[J]. Environmental Engineering, 2015, 33(S1): 920-923. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-HJGC2015S1230.htm
    [3]
    赵玲, 滕应, 骆永明. 我国有机氯农药场地污染现状与修复技术研究进展[J]. 土壤, 2018, 50(3): 435-445. https://www.cnki.com.cn/Article/CJFDTOTAL-TURA201803001.htm

    ZHAO Ling, TENG Ying, LUO Yongming. Status of organochlorine pesticide contaminated sites in China and advances in site remediation[J]. Soils, 2018, 50(3): 435-445. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-TURA201803001.htm
    [4]
    MAHMOODLU M G, HARTOG N, MAJID H S, et al. Oxidation of volatile organic vapours in air by solid potassium permanganate[J]. Chemosphere, 2013, 91(11): 1534-1538. doi: 10.1016/j.chemosphere.2012.12.035
    [5]
    MAHMOODLU M G, HASSANIZADEH S M, HARTOG N, et al. Evaluation of a horizontal permeable reactive barrier for preventing upward diffusion of volatile organic compounds through the unsaturated zone[J]. Journal of Environmental Management, 2015, 163: 204-213.
    [6]
    MAHMOODLU M G, HASSANIZADEH S M, HARTOG N, et al. Oxidation of trichloroethylene, toluene, and ethanol vapors by a partially saturated permeable reactive barrier[J]. Journal of Contaminant Hydrology, 2014, 164: 193-208. doi: 10.1016/j.jconhyd.2014.05.013
    [7]
    ZINGARETTI D, VERGINELLI I, LUISETTO I, et al. Horizontal permeable reactive barriers with zero-valent iron for preventing upward diffusion of chlorinated solvent vapors in the unsaturated zone[J]. Journal of Contaminant Hydrology, 2020, 234: 103687. doi: 10.1016/j.jconhyd.2020.103687
    [8]
    VERGINELLI I, CAPOBIANCO O, HARTOG N, et al. Analytical model for the design of in situ horizontal permeable reactive barriers (HPRBs) for the mitigation of chlorinated solvent vapors in the unsaturated zone[J]. Journal of Contaminant Hydrology, 2017, 197: 50-61. doi: 10.1016/j.jconhyd.2016.12.010
    [9]
    YAO Y J, VERGINELLI I, SUUBERG E M. A two-dimensional analytical model of vapor intrusion involving vertical heterogeneity[J]. Water Resources Research, 2017, 53(5): 4499-4513. doi: 10.1002/2016WR020317
    [10]
    FENG S J, ZHU Z W, CHEN H X, et al. Two-dimensional analytical solution for VOC vapor migration through layered soil laterally away from the edge of contaminant source[J]. Journal of Contaminant Hydrology, 2020, 233: 103664. doi: 10.1016/j.jconhyd.2020.103664
    [11]
    FENG S J, ZHU Z W, CHEN H X, et al. Two-dimensional analytical solution for subsurface volatile organic compounds vapor diffusion from a point source in layered unsaturated zone[J]. Journal of Contaminant Hydrology, 2021, 243: 103916. doi: 10.1016/j.jconhyd.2021.103916
    [12]
    XIE H J, WANG Q, BOUAZZA A, et al. Analytical model for vapour-phase VOCs transport in four-layered landfill composite cover systems[J]. Computers and Geotechnics, 2018, 101: 80-94. doi: 10.1016/j.compgeo.2018.04.021
    [13]
    MILLINGTON R J, QUIRK J P. Permeability of porous solids[J]. Transactions of the Faraday Society, 1961, 57(0): 1200-1207.
    [14]
    TALBOT A. The accurate numerical inversion of Laplace transforms[J]. IMA Journal of Applied Mathematics, 1979, 23(1): 97-120. doi: 10.1093/imamat/23.1.97
    [15]
    MILLS W B, LIU S, RIGBY M C, et al. Time-variable simulation of soil vapor intrusion into a building with a combined crawl space and basement[J]. Environmental Science & Technology, 2007, 41(14): 4993-5001.
    [16]
    DING X H, FENG, S J, ZHENG Q T, et al. A two-dimensional analytical model for organic contaminants transport in a transition layer-cutoff wall-aquifer system[J]. Computers and Geotechnics, 2020, 128: 103816.
    [17]
    US Environmental Protection Agency. Vapor Intrusion Database[DB/OL]. Washington, DC: US Environmental Protection Agency (EPA), 2012. https://www.epa.gov/vaporintrusion/vapor-intrusion-database.
    [18]
    US Environmental Protection Agency. Regional screening levels (RSLs)-generic tables[R/OL]. Washington, DC: US Environmental Protection Agency (EPA), 2021. https://www.epa.gov/risk/regional-screening-levels-rsls-generic-tables.
    [19]
    WALDEMER R H, TRATNYEK P G. Kinetics of contaminant degradation by permanganate[J]. Environmental Science & Technology, 2006, 40(3): 1055-1061.
    [20]
    ARONSON D, HOWARD P H. Anaerobic biodegradation of Organic Chemicals in Groundwater: A Summary of Field and Laboratory Studies[R]. North Syracuse: Environmental Science Center, Syracuse Research Corporation, 1997.
    [21]
    ABREU L D V, JOHNSON P C. Simulating the effect of aerobic biodegradation on soil vapor intrusion into buildings: Influence of degradation rate, source concentration, and depth[J]. Environmental Science & Technology, 2006, 40(7): 2304-2315.
    [22]
    US Environmental Protection Agency. Conceptual Model Scenarios for the Vapor Intrusion Pathway[R]. Washington, DC: US Environmental Protection Agency, 2012.

Catalog

    Article views (251) PDF downloads (76) Cited by()
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return