Advanced Search
  • 全国中文核心期刊
  • 中国科技核心期刊
  • 美国工程索引（EI）收录期刊
  • Scopus数据库收录期刊
Volume 41 Issue 5
Turn off MathJax
Article Contents
Abstract
References
ZHANG Zhi-hong, ZHANG Jia-pei. Adsorption model for multi-component heavy metal ions on clay based on non-equilibrium thermodynamics[J]. Chinese Journal of Geotechnical Engineering, 2019, 41(5): 829-835. DOI: 10.11779/CJGE201905005
Citation: ZHANG Zhi-hong, ZHANG Jia-pei. Adsorption model for multi-component heavy metal ions on clay based on non-equilibrium thermodynamics[J]. Chinese Journal of Geotechnical Engineering, 2019, 41(5): 829-835. DOI: 10.11779/CJGE201905005
shu

Adsorption model for multi-component heavy metal ions on clay based on non-equilibrium thermodynamics

  • The Key Laboratory of Urban Security and Disaster Engineering, Ministry of Education, Beijing University of Technology, Beijing 100124, China

More Information
  • Received Date: January 17, 2018
  • Published Date: May 24, 2019
    Graphical Abstract
    • Abstract
  • The adsorption behavior of clay particles is the key factor to control the solute transport, which can further affect the accurate evaluation of the long-term service performance of the seepage prevention barrier. Based on the single-component adsorption model, the theory of non-equilibrium thermodynamics and Ziegler's principle of maximal rate of dissipation, a non-equilibrium adsorption model for multi-components under non-ideal system is established by using the continuum mechanics method through setting up the dispersion-type free energy function and dissipation rate function. The proposed model is employed to describe the adsorption process of heavy metal ions. The results show that there is a good agreement between the model and experimental results, and it is indicated that the proposed non-equilibrium adsorption model can correctly reveal the kinetics mechanism of adsorption process for multi-components on clay.
    • FullText(HTML)
    • References (43)
  • [1]
    LANGMUIR I.The adsorption of gases on plane surfaces of glass, mica and platinum[J]. Journal of Chemical Physics, 2015, 40(12): 361-403.
    [2]
    HATFIELD. Colloid & capillary chemistry[M]. London: Methuen, 1926.
    [3]
    DUBININ M M, RADUSHKEVICH L V.Equation of the characteristic curve of activated charcoal[J]. Zhurnal Nevropatologii I Psikhiatrii Imeni Sskorsakova, 1947, 79(7): 843-848.
    [4]
    谢海建, 陈仁朋, 陈云敏, 等. 考虑非线性吸附时污染物在半无限黏土中的一维扩散解[J]. 岩土工程学报, 2007, 29(9): 1404-1408.
    (XIE Hai-jian, CHEN Ren-peng, CHEN Yun-min, et al.Analytical solution of contaminant diffusion through semi-infinite clay under non-linear adsorption condition[J]. Chinese Journal of Geotechnical Engineering, 2007, 29(9): 1404-1408. (in Chinese))
    [5]
    何宏平, 郭九皋, 朱建喜, 等. 蒙脱石、高岭石、伊利石对重金属离子吸附容量的实验研究[J]. 岩石矿物学杂志, 2001, 20(4): 573-578.
    (HE Hong-ping, GUO Jiu-gao, ZHU Jian-xi, et al.An experiment study of adsorption capacity of montmorillonite, kaolinite and illite for heavy metals[J]. Acta Petrologica et Mineralogica, 2001, 20(4): 573-578. (in Chinese))
    [6]
    ROWE R K, QUIGLEY R M, BRACHMAN, et al. Barrier systems for waste disposal facilities[M]. London, New York: SponPress, 2004.
    [7]
    YONG R N, MOHAMED A M O, WARKENTIN B P. Principles of contaminant transport in soils[M]. New York: Elsevier, 1992: 206-234.
    [8]
    谢海建, 陈仁朋, 陈云敏, 等. 考虑非线性吸附时溶质在有限厚度黏土中的一维扩散解[J]. 环境科学学报, 2008, 28(2): 376-383.
    (XIE Hai-jian, CHEN Ren-peng, CHEN Yun-min, et al.An analytical solution of solute diffusion through soils with finite depth under non-linear adsorption conditions[J]. Acta Science Circumstantiae, 2008, 28(2): 376-383. (in Chinese))
    [9]
    BOYD G E, JR M L, ADAMSON A W.The exchange adsorption of ions from aqueous solutions by organic zeolites; performance of deep adsorbent beds under non-equilibrium conditions[J]. Journal of the American Chemical Society, 1947, 69(11): 2818.
    [10]
    SHEINDORF C, REBHUN M, SHEINTUCH M.A freundlich-type multicomponent isotherm[J]. Journal of Colloid & Interface Science, 1981, 79(1): 136-142.
    [11]
    WELP G, BRÜMMER G W. Effects of organic pollutants on soil microbial activity: the influence of sorption, solubility, and speciation[J]. Ecotoxicology & Environmental Safety, 1999, 43(1): 83.
    [12]
    王艳, 唐晓武, 刘干斌, 等. Mn(II)、Cr(III)在黄土上共存吸附特性研究[J]. 岩土工程学报, 2015, 37(8): 1497-1502.
    (WANG Yan, TANG Xiao-wu, LIU Gan-bin, et al.Adsorption behavior of co-existing Mn(II) and Cr(III) in loess soil[J]. Chinese Journal of Geotechnical Engineering, 2015, 37(8): 1497-1502. (in Chinese))
    [13]
    UNUABONAH E I, OLU-OWOLABI B I, ADEBOWALE K O. Competitive adsorption of metal ions onto goethite-humic acid-modified kaolinite clay[J]. International Journal of Environmental Science & Technology, 2016, 13(4): 1043-1054.
    [14]
    COVELO E F, ANDRADE M L, VEGA F A.Heavy metal adsorption by humic umbrisols: selectivity sequences and competitive sorption kinetics[J]. J Colloid Interface Sci, 2004, 280(1): 1-8.
    [15]
    张金利, 史艳婷, 杨庆. 白陶瓷土对多元重金属体系吸附特性研究[J]. 岩土工程学报, 2017, 39(5): 916-923.
    (ZHANG Jin-li, SHI Yan-ting, YANG Qing.Adsorption behaviors of multi-element heavy metal on white pottery clay[J]. Chinese Journal of Geotechnical Engineering, 2017, 39(5): 916-923. (in Chinese))
    [16]
    陈云敏, 王誉泽, 谢海建, 等. 黄土-粉土混合土对Pb(II)的静平衡和动态吸附特性[J]. 岩土工程学报, 2014, 36(7): 1185-1194.
    (CHEN Yun-min, WANG Yu-ze, XIE Hai-jian, et al.Adsorption characteristics of loess-modified natural silt towards Pb(II): equilibrium and kinetic tests[J]. Chinese Journal of Geotechnical Engineering, 2014, 36(7): 1185-1194. (in Chinese))
    [17]
    XIE H J, CHEN Y M, LOU Z H, et al.An analytical solution to contaminant diffusion in semi-infinite clayey soils with piecewise linear adsorption[J]. Chemosphere, 2011, 85(8): 1248-1255.
    [18]
    WANG Y Z, CHEN Y M, XIE H J, et al.Lead adsorption and transport in loess-amended soil-bentonite cut-off wall[J]. Engineering Geology, 2016, 215: 69-80.
    [19]
    NKEDIKIZZA P, RAO P S C, JESSUP R E, et al. Ion exchange and diffusive mass transfer during miscible displacement through an aggregated oxisol[J]. Journal of the Soil Science Society of America, 1982, 46(3): 211-213.
    [20]
    BRUSSEAU M L, RAO P S C. Modeling solute transport in structured soils: a review[J]. Geoderma, 1990, 46(1): 169-192.
    [21]
    陈记文, 薛强, 刘磊, 等. 非平衡吸附模型在研究渗滤液对土壤污染影响中的应用[J]. 岩土力学, 2006, 27(12): 2186-2190.
    (CHEN Ji-wen, XUE Qiang, LIU Lei, et al.Application of non-equilibrium adsorption model to study of influence of waste landfill leachate on soil pollution[J]. Rock and Soil Mechanics, 2006, 27(12): 2186-2190. (in Chinese))
    [22]
    梁冰, 赵颖, 薛强, 等. 土壤中污染物迁移转化规律的数值模拟研究[J]. 岩土力学, 2008, 29(9): 2373-2377.
    (LIANG Bing, ZHAO Ying, XUE Qiang, et al.Research on numerical simulation of contaminant transportation and transformation in soil[J]. Rock and Soil Mechanics, 2008, 29(9): 2373-2377. (in Chinese))
    [23]
    AND J J P, XING B. Mechanisms of slow sorption of organic chemicals to natural particles[J]. Environmental Science & Technology, 2016, 30(1): 1-11.
    [24]
    QIU H, LU L V, PAN B C, et al.Critical review in adsorption kinetic models[J]. Journal of Zhejiang University, 2009, 10(5): 716-724.
    [25]
    AZIZIAN S, BASHIRI H, ILOUKHANI H.Statistical rate theory approach to kinetics of competitive adsorption at the solid/solution interface[J]. Journal of Physical Chemistry C, 2008, 112(27): 10251-10255.
    [26]
    刘继芳, 曹翠华, 蒋以超, 等. 重金属离子在土壤中的竞争吸附动力学初步研究: Ⅰ竞争吸附动力学的竞争规律与竞争系数[J]. 中国土壤与肥料, 2000(2): 30-101.
    (LIU Ji-fang, CAO Cui-hua, JIANG Yi-chao, et al.Preliminary study on the dynamics of competitive adsorption of heavy metals in soils(Ⅰ)[J]. Soil and Fertilizer Science in China, 2000(2): 30-101. (in Chinese))
    [27]
    LIU S.A mathematical model for competitive adsorptions[J]. Separation & Purification Technology, 2015, 144: 80-89.
    [28]
    KÄRGER J, BÜLOW M. Theoretical prediction of uptake behaviour in adsorption kinetics of binary gas mixtures using irreversible thermodynamics[J]. Chemical Engineering Science, 1975, 30(8): 893-896.
    [29]
    PAGONABARRAGA I, RUB J M.Derivation of the langmuir adsorption equation from non-equilibrium thermodynamics[J]. Physica A Statistical Mechanics & Its Applications, 1992, 188(4): 553-567.
    [30]
    SANTAMARIAHOLEK I, GRZYWNA Z J, RUBI J M.A non-equilibrium thermodynamics model for combined adsorption and diffusion processes in micro-and nanopores[J]. Journal of Non-Equilibrium Thermodynamics, 2012, 37(3): 273-290.
    [31]
    BENNETHUM L S, CUSHMAN J H.Multiscale, hybrid mixture theory for swelling systems: Ⅰ balance laws[J]. International Journal of Engineering Science, 1996, 34(34): 125-145.
    [32]
    HASSANIZADEH M, GRAY W G.General conservation equations for multi-phase systems: 1 Averaging procedure[J]. Advances in Water Resources, 1979, 2(1): 131-144.
    [33]
    黄璐. 基于混合物理论的污染物输运模型研究[D]. 北京: 北京交通大学, 2010.
    (HUANG Lu.Contaminant transport model research based on the mixture theory[D]. Beijing: Beijing Jiaotong University, 2010. (in Chinese))
    [34]
    ZIEGLER H.An introduction to thermomechanics[M]. Oxford: North Holland, 1977.
    [35]
    LEBON G, JOU D, CASAS-VÁZQUEZ J. Understanding non-equilibrium thermodynamics[M]. New York: Springer, 2008: 445-457.
    [36]
    段辉. 对“S型曲线“城市化理论的再讨论[J]. 技术经济与管理研究, 2015(10): 119-123.
    (DUAN Hui.Discussion on “S curve“ theory of urbanization[J]. Technoeconomics & Management Research, 2015(10): 119-123. (in Chinese))
    [37]
    LINS Y, ZOU Y, SCHANZ T.Physical modeling of SWCC for granular materials[M]// Theoretical and Numerical Unsaturated Soil Mechanics. Heidelberg: Springer, 2007: 61-74.
    [38]
    LU N.Generalized soil water retention equation for adsorption and capillarity[J]. Journal of Geotechnical & Geoenvironmental Engineering, 2016, 142(10): 04016051.
    [39]
    马荔, 陈虹锦. 基础化学[M]. 2版. 北京: 化学工业出版社, 2011.
    (MA Li, CHEN Hong-jin.Chemistry fundamental[M]. 2nd ed. Beijing: Chemical Industry Press, 2011. (in Chinese))
    [40]
    王慧娟, 韩光泽. 化学势的普遍化表达式及其应用[J]. 华北电力大学学报(自然科学版), 2012, 39(1): 109-112.
    (WANG Hui-juan, HAN Guang-ze.The generalized expression of chemical potential and its application[J]. Journal of North China Electric Power University, 2012, 39(1): 109-112. (in Chinese))
    [41]
    ETCI Ö, BEKTAŞ N, ÖNCEL M S. Single and binary adsorption of lead and cadmium ions from aqueous solution using the clay mineral beidellite[J]. Environmental Earth Sciences, 2010, 61(2): 231-240.
    [42]
    ZHANG H, NIU Z W, LIU Z, et al.Equilibrium, kinetic and thermodynamic studies of adsorption of Th(Ⅳ) from aqueous solution onto kaolin[J]. Journal of Radioanalytical and Nuclear Chemistry, 2014, 303: 87-97.
    [43]
    刘娟娟. 铜、铬单一及复合体系在两种黏土矿物中吸附的差异及其机理研究[D]. 杨凌: 西北农林科技大学, 2014.
    (LIU Juan-juan.Adsorption behavior and mechanism of copper and chromium onto two clay minerals in Cu-Cr single and binary solutions[D]. Yanglin: Northwest A&F University, 2014. (in Chinese))
    • Related Articles
  • Supplements (0)

  • Cited by

    Periodical cited type(4)

    1. 朱剑锋，夏亚宁，鞠露莹，杨浩. 固化土双向制样仪研发与制样效果多尺度对比. 实验技术与管理. 2024(01): 193-200 .
    2. 朱剑锋，杨浩，徐日庆，潘斌杰，饶春义. 硫氧镁水泥固化沿海风电场滩涂软土加固机理及微观特性分析. 太阳能学报. 2022(07): 276-283 .
    3. 王强，李操，葛单单，王潇. 疏浚淤泥固化处理研究进展. 安徽建筑. 2022(12): 144-147 .
    4. 朱剑锋，徐日庆，罗战友，饶春义. 考虑3种因素影响的硫氧镁水泥固化土修正邓肯-张模型. 中南大学学报(自然科学版). 2020(07): 1989-2001 .

    Other cited types(4)

Catalog

    Get Citation
    PDF
    XML
    Article views PDF downloads Cited by(8)
    Related
    Copyright © 2010 Editorial By Chinese Journal of Geotechnical Engineering 苏ICP备05007122号-11公安联网备案号：32010602011255
    Editorial Office address：34 Hujuguan,Nanjing 210024,ChinaPostal Code：210024Tel：025-85829534，85829556E-mail: ge@nhri.cn

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return